A highly polished early 16th-century Welsh buckler shield.

Investigating a sixteenth century Welsh buckler

The question

Centuries of cleaning had left this small shield in a highly polished state. Could XRF provide clues to its original appearance?

Results of analysis

XRF analysis was used to examine many parts of the surface. The raised rings were shown to have originally been tinned, whilst the backing was found to be painted with a (red) lead based compound. The brass rivet heads, despite being of two different shapes were all of low zinc brass, consistent with the date of the shield.

Significance

Analysis helped show that the buckler’s original appearance would have been significantly different from what is seen today, with alternate bands of bright tin and deep red paint.

Outcome

This work not only enabled a more accurate description of the object to be recorded, but has used in a number of presentations as an example of everyday analytical investigations of objects in the Science Lab.

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First commercial steel melting

Benjamin Huntsman of Sheffield is widely credited with the first commercial melting of steel in around 1740, using his crucible process. However, the melting of steel had long been practiced in central Asia and India and was known as Damascus steel.